To promote the high-quality development of high-end polyolefin, the development of highly efficient heterogeneous catalysts for the telomerization of 1,3-butadiene and methanol to the linear product (1-methoxy-2,7-octadiene, 1-MOD) has received considerable attention. However, current heterogeneous catalysts suffer from low catalytic activity, low selectivity, and poor stability. Therefore, achieving high stability and efficient telomerization has become an urgent issue that needs to be addressed in this field.