Transition metal selenides have been considered to be a good choice for electrocatalytic water splitting. In addition, Metal-organic frameworks (MOFs) have been used to make catalysts with good electrocatalytic capabilities. Traditionally, the MOF-derived selenides are produced via the self-sacrificing MOF template methods. However, this strategy is high-energy consuming, and it is difficult to precisely control the structure and component homogeneity of the product during pyrolysis.