Photoluminescent molecules, capable of absorbing and re-emitting light, play an important role in the development of technologies such as light-emitting diodes, sensors, and displays. Among them, ordered arrangements of π-electronic molecules such as crystals of organoplatinum(II) complexes, where a platinum(II) ion is coordinated by organic ligands in a square-planar arrangement, stand out for their applications in energy-efficient flexible displays.